A series of three articles from the Uphill Athlete website about fat adaptation. The quote below is from the first article, as is the link enclosed.
"As highlighted above, because carbohydrate ingestion before and during endurance exercise of low to moderate intensity (Zones 1 and 2) reduces the body's ability to utilize fat as a fuel source (5), the goal of every endurance athlete should be to train the body to use a greater contribution of fat as a source of energy (for example, by training in a fasted state). This also has the added benefit of reducing the body's reliance on eating carbohydrates during endurance exercise, thus sparing muscle glycogen levels. This enables you to tap into your carbohydrate store when you need it the most, during those higher-intensity moments—on steep climbs, when you pick up the pace to get down before dark, and through strenuous moves or cruxes on a long alpine route. This is known as fat adaptation."